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Metal Science and Metal Physics
ArticleName Effect of modifiers on 35KhML steel structure and properties
DOI 10.17580/chm.2026.04.11
ArticleAuthor U. M. Khalikulov, E. S. Nabiev, S. R. Khudoyarov, M. Z. Ubaydullaev, E. I. Ruklinskaya
ArticleAuthorData

Almalyk State Technical Institute, Almalyk, Uzbekistan

U. M. Khalikulov, Dr. Eng., Associate Prof., Acting Rector, e-mail: utkirhm@mail.ru

 

NUST MISIS, Almalyk Branch, Almalyk, Uzbekistan
E. S. Nabiev, Cand. Eng., Associate Prof., Dept. of Metallurgy of Ferrous, Non-Ferrous, and Rare Metals, e-mail: nes.2406@mail.ru
S. R. Khudoyarov, Dr. Eng., Associate Prof., Deputy Director, e-mail: suleyman0677@yandex.ru
M. Z. Ubaydullaev, Assistant, Dept. of Metallurgy of Ferrous, Non-Ferrous, and Rare Metals, e-mail: muzacamper@gmail.com
E. I. Ruklinskaya, Assistant, Dept. of Metallurgy of Ferrous, Non-Ferrous, and Rare Metals, e-mail: ruklinskayaelena97@yandex.ru

Abstract

This paper presents the results of a study on the influence of modifiers on the microstructure, wear resistance, and impact toughness of chromium-molybdenum steel used at JSC Almalyk Mining and Metallurgical Plant for the manufacture of cast parts for mining machinery and processing equipment. The study involved modified samples of 35KhML steel. Vanadium, molybdenum, and aluminum-calcium ferrovanadium nanopowders were used as modifiers. It was established that the optimal result for all studied parameters is achieved with modification with molybdenum nanopowder. This demonstrates the high efficiency of molybdenum as a nanomodifier, promoting the formation of a finely dispersed structure with a uniform distribution of carbides. However, from the standpoint of the technical and economic feasibility of producing modified chromium-molybdenum steel, the use of a complex Fe-V-Al-Ca modifier appears promising, providing an acceptable level of properties at significantly lower unit costs. The formation of stable vanadium carbonitrides and modified non-metallic inclusions under the influence of calcium and aluminum creates conditions for the formation of favorable structures, which facilitates the effective dissipation of impact energy and prevents the development of brittle cracks. The introduction of modifiers has been shown to refine and thin dendrites, promoting their more uniform distribution within the structure compared to the unmodified state. Annealed modified steel has a fine-grained structure with predominantly elongated ferrite grains. After quenching and tempering, the modified steel acquires a sorbitic structure. The results obtained can serve as a basis for the development of high-quality chromium-molybdenum steels used for the manufacture of cast articles.

keywords Chromium-molybdenum steel, steel modification, modifiers, metal nanopowders, metal microstructure, wear resistance, impact toughness
References

1. Khalikulov U. M. Quality requirements for chromium-molybdenum steel regarding non-metallic inclusions. International scientific research of problems of science and education. International conference. Paris. France. 2025. pp. 60–64.
2. Khalikulov U. M., Khasanov A. S., Dzheparovа M. N. Modern Trends in Heat Treatment of Chromium Molybdenum Steel. The American Journal of Interdisciplinary Innovations and Research. 2025. Vol. 07. Iss. 03. pp. 23–27. DOI: 10.37547/tajiir/Volume07Issue03-05
3. Khalikulov U. M., Khasanov A. S., Dzheparovа M. N. Integration of the modifier into the technological process of chrome molybdenum steel production to enhance mechanical properties. The American Journal of Engineering and Technology. 2025. Vol. 06. Iss. 12. pp. 190–198. DOI: 10.37547/tajet/Volume06Issue12-18
4. Marukovich E. I., Stetsenko V. Yu. Modification efficiency increasing. Lityo i metallurgiya. 2006. No. 2 (38). pp. 151–153.
5. Polishko S. O. Complex influence of chemical modification elements on improving the quality of wheel steel during out-of-furnace processing of its melts. Metallofizika i noveyshie tekhnologii. 2023. No. 45 (1). pp. 127–135. DOI: 10.15407/mfint.45.01.0127
6. Afonaskin A. V., Dudorov V. I., Dudorov T. A. Selection of the modifying alloy (ligature) composition for steel and cast iron castings. Vestnik KGU. 2010. No. 1. pp. 108–110.
7. Minnekhanov G. N., Shuykin O. A., Minnekhanov R. G. Effect of modification with titanium carbonitride nanoparticles and alloying with titanium on the structure and properties of hypoeutectic cast irons. Omskiy nauchny vestnik. 2009. No.1. pp. 22–24.
8. Wang X., Wu Z., Li B., Chen W., Zhang J., Mao J. Inclusions modification by rare earth in steel and the resulting properties: A review. Journal of Rare Earths. 2024. Vol. 42. Iss. 3. pp. 431–445.
9. Komarov O. S., Volosatikov V. I., Provorova I. B. Complex modification of steel. Metallovedenie i termicheskaya obrabotka metallov. 2013. No. 3 (693). pp. 48–51.
10. Rosenberg E. V., Baranovsky K. E., The effect of complex modifiers on low-carbon wear-resistant steels. Modern technologies for blank production. Collection of scientific papers of the Republican Scientific and Technical Conference of the faculty, researchers, doctoral students, and postgraduate students of the Faculty of Mathematics and Technical Sciences of the Belarusian National Technical University, Minsk: BNTU. 2022. pp. 59–61.
11. Bakin I. V., Mikhailov G. G., Golubtsov V. A., Ryabchikov I. V. Methods for improving the efficiency of steel modifying. Materials Science Forum. 2019. Vol. 946. pp. 215–222.
12. Rozhikhina I. D., Nokhrina O. I., Dmitrienko V. I., Platonov M. A. Modification of steels with barium and strontium. Izvestiya vysshikh uchebnykh zavedeniy. Chernaya metallurgiya. 2015. No. 12. Vol. 58. pp. 871–876.
13. Bykov P. O., Tusupbekova M. Zh., Absolyamova D. R., Deygraf I. E. Modification of steel for seamless pipes production. Nauka i tekhnika Kazakhstana. 2022. No. 1. pp. 62–69.
14. Rudnitsky F. I., Stasyulevich V. A., Traymak N. S. Study of the influence of modification on the structure, phase composition and properties of 5KhNM cast steel. Lityo i metallurgiya. 2006. No. 4. pp. 104–106.
15. Shmyrko V. I., Lavrenko A. S., Dudnik G. I. The influence of modification on properties of medium-carbon and low-alloy steels. Novye materialy i tekhnologii v metallurgii i mashinostroenii. 2007. No. 1. pp. 147–149.
16. Shub L. G., Recommendations for steel modification. Theory and practice of metallurgical processes in the production of ferrous alloy castings. Collection of Papers of the Foundry Council No. 2, Chelyabinsk: Chelyabinskiy Dom pechati, 2007. 120 p.
17. Ryabchikov I. V., Bakin I. V., Mizin V. G., Golubtsov V. A. Modification and microalloying of steel with complex alloys with chemically active elements is an effective method for improving the quality of metal products. Stal. 2018. No. 12. pp.18–21.
18. Kovalev P. V., Ryaboshuk S. V., Issagulov A. Z., Ibatov М. K., Kvon Sv. S., Kulikov V. Y. Studying nanopowder modifiers (npm) effect on structure and properties steels. Metalurgija. 2020. Vol. 59 Iss. 4. pp. 551–554.
19. Khalikulov U. M., Khasanov A. S., Dzheparov M. N. Aspects of modification and crystallization of high-alloy steels. The American Journal of Applied Sciences. 2025. Vol. 07. Iss. 03. pp. 20–25. DOI: 10.37547/tajas/Volume07Issue03-04
20. Poluboyarova V. A., Korotaeva Z. A., Zhdanoka A. A., Kuznetsov V. A. Nanodisperse modification of 110G13L steel. Zhurnal Sibirskogo federalnogo universiteta. Tekhnika i tekhnologii. 2016. No. 9 (1). pp. 117–125.
21. Kuzmenko A. G., Vishnevsky O. A. Method of testing for abrasive wear using the Brinell-Howarth (BR - HV) scheme. Part I. Theoretical foundations of the method. Problemy tribologii. 2012. No. 4. pp. 102–108.
22. GOST 9454-78. Metals. Testing method for impact bending at low, room and elevated temperatures. — Intr. 01.01.1979.

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