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| ArticleName | New catalyst systems for determination of Ir (IV) and Rh (III) at their joint presence in the solution |
| ArticleAuthor | Kapustina Е. V., Burmistrova N. A., Mushtakova S. P. |
| ArticleAuthorData | Kapustina Е. V., e-mail: kkapustina@mail.ru |
| Abstract | The high-sensitivity differential kinetic method based on joint catalytical action of compounds of platinum metals in indicator oxidation reactions of aromatic amines is offered for simultaneous quantitative definition Ir (IV) and Rh (III) in the solution. Influence of structure of molecules of arylamines on kinetic of courses of processes of their catalytical oxidation, on characteristics of joint determination of catalysts is discussed. The estimation of synergistic effect of Ir (IV) and Rh (III) on speed of indicator oxidation reactions of aromatic amines by periodate-ions is realized. |
| keywords | Platinum metals, iridium, rhodium, joint determination, aromatic amines, catalimetry. |
| References | 1. Zolotov Yu. A., Varshal G. M., Ivanov V. M. Analiticheskaya khimiya metallov platinovoy gruppy. – M. : Editorial URSS, 2003. – 592 p. 2. Mushtakova S. P., Kraskova T. P., Gumenyuk A. P., Romanova E. I. // Zhurnal analiticheskoy khimii. 1988. V. 43, № 11. P. 2014. 3. Mushtakova S. P., Gumenyuk A. P., Aleshina V. V. // Ibid. 1986. V. 41, № 8. P. 1400. 4. Mushtakova S. P., Gumenyuk A. P., Khmelev S. S., Batasheva N. A. // Ibid. 1993. V. 48, № 7. P. 1218. 5. Mushtakova S. P., Gumenyuk A. P., Kozhina L. F., Shtykova S. S. // Ibid. 1999. V. 54, № 7. P. 749. 6. Nikonorov P. G., Mushtakova S. P., Burmistrova N. A., Kozhina L. F. // Ibid. 2004. V. 59, № 2. P. 161. 7. Nikonorov P. G., Burmistrovs N. A., Mushtakova S. P. // Ibid. 2008. V. 63, № 4. P. 432. 8. PeresBendito D., Sil'va M. Kineticheskie metody v analiticheskoy khimii. - M. : Mir, 1991. - 395 p. 9. Kapustina E. V., Burmistrova N. A., Mushtakova S. P. // Zhurnal analiticheskoy khimii. 2006. V. 61, № 3. P. 305. 10. Worthington J. B., Pardue H. L. // Analytical Chemistry. 1970. Vol. 42. P. 1157. 11. Khayamian T., Ensafi Ali A., Atabati M. // Analytical Letters. 2002. Vol. 35, N 12. P. 2039–2052. |
| Language of full-text | russian |
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