Journals →  Tsvetnye Metally →  2011 →  #3 →  Back

The problems of environment protection in metallurgy
ArticleName Elaboration of the potassium and sodium ferrates (VI) syntesis by a self-sustaining combustion method
ArticleAuthor Ul'yanova M. A., Rylov Yu. B., Andreev V. P., Putin S. B.
ArticleAuthorData M. A. Ul'yanova, Head of Laboratory No. 2, Department of Chemistry and New Chemical Technologies, e-mail:; Yu. B. Rylov, Jounior Researcher; V. P. Andreev, Researcher; S. B. Putin, The First Depury Director, Deputy Director of Scientific Work, The Roskhimzashita Corporation.
The possibility of the potassium and sodium ferrate (VI) obtaining by a self-sustaining combustion method characterized by a high content of basic substance and low power consumption is experimentally confirmed. The main parameters affecting the ferrates (VI) synthesis process, such as pressing density, residual moisture of the initial components, content of active oxygen in the initial peroxide compounds are established. Optimum ratio of the initial components is given along with conditions of their intercation allowing to obtain high-grade ferrates (VI).
keywords Ferrates (VI) synthesis, self-sustaining combustion, endothermic reaction, peroxide compounds, pressing density, residual moisture, active oxigen.

1. Kokarovtseva I. G., Belyaev I. N., Semenyakova L. V. Uspekhi khimii. Russian Chemical Reviwes. 1972. Vol. 41. pp. 1978–1993.

2. Patent 4405573 SShA, NKI 423/150.1. Process for preparing potassium ferrate. Paul J., Ronald L. ; published 20.09.1983.

3. Patent 9913389 France, MPK S 01 G 49/02. Procèdè de synthиse par voie solide de ferrates de mètaux alcalins ou alcalino-terreux et ferrates ainsi obtenus. Caballah I., Evrard O., Kanari N., Neveux N. ; published. 27.04.2001.

4. Patent 2316477 RF, MPK C 01 G 49/00. Sposob polucheniya ferrata kaliya. Method of obtaining potassium ferrate. Andreev V. P., Ulyanova M. A., Ulyanova T. P., Ferapontov Yu. A., Shelkovnikova N. A. ; asserted 27.03.2006 ; published 10.02.2008, Bulletin No. 4.

5. Patent 2371392 RF, MPK C 01 G 49/00. Sposob polucheniya ferrata (VI) kaliya. Method of obtaining potassium ferrate (VI). Ulyanova M. A., Andreev V. P., Ferapontov Yu. A., Rylov Yu. B. ; asserted 12.02.08. ; published 27.10.09 ; Bulletin No. 30.

6. Patent 2356842 RF, MPK C 01 G 49/00, C 01 D 13/00. Sposob polucheniya ferrata (VI) natriya. Method of obtaining sodium ferrate (VI). Andreev V. P., Rylov Yu. B., Ul'yanova M. A., Ferapontov Yu. A. ; asserted 09.08.2007 ; published 27.05.2009 ; Bulletin No. 15.

7. Ulyanova M. A., Dvoretskiy S. I., Ferapontov Yu. A., Andreev V. P., Rylov Yu. B. Vestnik TGTU. Bulletin of the Tambov State Technical University. Tambov, 2009. Vol. 15, No. 4. pp. 855–860.

8. Kheyker D. M., Zevin L. S. Rentgenovskaya difraktometriya (X-ray diffractometry). Moscow, 1963. 380 pp.

9. Shidlovskiy A. A. Osnovy pirotekhniki (Fundamentals of pyrotechnics). Moscow, 1964. 340 pp.

Language of full-text russian
Full content Buy