Журналы →  Tsvetnye Metally →  2021 →  №8 →  Назад

HEAVY NON-FERROUS METALS
Название Use of thermochemistry methods when processing oxidized nickel ores
DOI 10.17580/tsm.2021.08.05
Автор Kolmachikhina O. B., Lobanov V. G., Polygalov S. E., Makovskaya O. Yu.
Информация об авторе

Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russia:

O. B. Kolmachikhina, Associate Professor, Сandidate of Technical Sciences, e-mail: o.b.kolmachikhina@urfu.ru
V. G. Lobanov, Associate Professor, Сandidate of Technical Sciences, e-mail: v.g.lobanov@urfu.ru
S. E. Polygalov, Assistant Lecturer, e-mail: sergey.polygalov@urfu.ru
O. Yu. Makovskaya, Associate Professor, Сandidate of Technical Sciences, e-mail: o.i.makovskaia@urfu.ru

Реферат

About 60–70% of the surface reserves of nickel are concentrated in oxidized (laterite) ores. Approximately 40% of nickel is produced from this type of raw material. Due to the depletion of nickel sulfide ores and the growing demand for metal, interest in the processing of oxidized ores is growing, despite the low content of a valuable component (0,75–1%) and some difficulties of processing them. Currently in non-ferrous metallurgy various pyrometallurgical, hydrometallurgical or combined pyro-hydrometallurgical methods of processing of oxidized nickel ores with obtaining metallic nickel and cobalt or their compounds are employed. Significant reserves of oxidized nickel ores are located in the Urals: in the Chelyabinsk, Sverdlovsk and Orenburg regions. Reducing-sulphidizing smelting of laterite ore to produce fire nickel, which has been used at Ural enterprises for many years, is not profitable in the current economic conditions. The widespread of hydrometallurgical technologies is hindered by the high cost of reagents and the unsatisfactory extraction of valuable components from ores. One of the options for improving such technologies may be the use of thermochemical methods, as preparatory stage for opening resistant nickel-containing minerals. The paper presents the results of studies of high-temperature sulfatization of the Ural oxidized ores. The choice of reagent is due to the availability and low price of sulfuric acid. It was shown that at an acid consumption of 0,7 g per 1 g of ore and at a sulfatization temperature of 420 oC, the maximum nickel recovery in solution is 80–82%. The hard filterability of the obtained pulps determines the feasibility of considering such technological methods for the extraction of Ni and Co, as sorption leaching. The use of sorption extraction of nickel from leaching solutions is possible after their preliminary purification from iron. Promising are chelating selective ion exchangers.

Ключевые слова Nickel, cobalt, oxidized nickel ores, thermochemical treatment, leaching, sorption
Библиографический список

1. Chuvashov P. Yu., Vatolin N. A., Khalezov B. D., Zelenin E. A., Petrova S. A. et al. Developing a heap leaching process for recovering nickel from off-grade oxidized nickel ores of the Serov deposit. Fundamentals of processing and disposal of man-made waste. Tekhnogen-2012. Proceedings of the international congress marking the 80 th anniversary of the Ural science. Yekaterinburg, 2012. pp. 431–437.
2. Orlov S. L., Baskov D. B. Method of underground leaching of oxidised nickel ores, containing ferrous and magnesia ores. Patent RF, No. 2353754. Applied: 31.08.2006. Published: 27.04.2009.
3. Khalezov B. D., Gavrilov A. S., Petrova S. A., Reutov D. S., Melchakov S. Yu. Heap leaching of oxidized nickel ores. Metallurg. 2019. No. 1. pp. 59–64.
4. Selivanov E. N., Sergeeva S. V., Gulyaeva R. I. The oxidized nickel ores of the Urals: Composition, thermal properties, processing technology. Proceedings of the Russian meeting with international participants: The Role of Mineralogical Techniques in the Rational Use of Natural Resources. Moscow, 15–16 May 2018. Moscow : VIMS, 2018. pp. 181–184.

5. Sadykhov G. B., Anisonyan K. G., Kopiev D. Yu., Olyunina T. V., Zablotskaya Yu. V. et al. New comprehensive approaches to the use of oxidized nickel ore. Research papers of the Baykov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences. Moscow : Interkontakt Nauka, 2018. 644 p.
6. Reznik I. D., Ermakov G P. The problems of processing the oxidized nickel ores of the Buruktal deposit. Tsvetnye Metally. 2001. No. 9. pp. 23–30.
7. Kalashnikova M. I., Shneerson Ya. M., Saltykov P. M., Kostikov M. V. Hydrometallurgical processing of oxidized nickel ores. Tsvetnye Metally. 2003. No. 12. pp. 22–28.
8. Ryzhova S. O., Talovina I. V., Lazorenkov V. G., Vorontsova N. I., Ugolkov V. L. The nickel-bearing oxides of iron from the Buruktal deposit, South Urals. Zapiski Gornogo instituta. 2009. Vol. 183. pp. 101–111.
9. Naboychenko S. S., Shneerson Ya. M. Pressure hydrometallurgy of nonferrous metals. Yekaterinburg : GOU UGTU-UPI. 2002. 940 p.
10. Senchenko A. E., Rybkin S. G., Aksenov A. V., Grinkevich A. V. Method of processing oxidized nickel ores. Patent RF, No. 2596510. Applied: 22.05.2015. Published: 10.09.2016. Bulletin No. 25.
11. Sinegribov V. A., Koltsov V. Yu., Logvinenko I. A., Melnik D. V., Batshev V. I. Method of reprocessing of the oxygenated nickel-cobalt ores. Patent RF, No. 2287597. Applied: 27.08.2004. Published: 20.11. 2006. Bulletin No. 32.
12. Kuzmin V. I., Kuzmin D. V. Sorption of nickel and copper from leach pulps of low-grade sulfide ores using Purolite S930 chelating resin. Hydrometallurgy. 2014. Vol. 141. pp. 76–81.
13. Sole K. C. The Evolution of Cobalt – Nickel Separation and Purification Technologies: Fifty Years of Solvent Extraction and Ion Exchange. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. pp. 1167–1191.
14. Botelho Junior A. B., Espinosa D. C. R., Dreisinger D., Tenório J. A. S. Recovery of Nickel and Cobalt from Nickel Laterite Leach Solution Using Chelating Resins and Pre-Reducing Process. The Canadian Journal of Chemical Engineering. 2019. Vol. 97, Iss. 5. pp. 1181–1190.
15. Alosmanov R. M. Understanding the kinetics of cobalt and nickel ion sorption with phosphorus-containing cationite. Sorbtsionnye i khromato graficheskie protsessy. 2010. Vol. 10, No. 3. pp. 427–432.
16. Saykova S. V., Panteleeva M. V., Saykova D. I. Cation exchange processing of buruktal oxidized nickel ore autoclave solutions. Tsvetnye Metally. 2019. No. 9. pp. 16–21. DOI: 10.17580/tsm.2019.09.02.
17. Dudareva G. N., Irinchinova N. V. Recovery of nickel by sorption as part of the chlorine-ammonium technique for oxidized ore processing. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologiya. 2016. Vol. 6, No. 2. pp. 83–89.
18. Kolmachikhina O. B., Napolskikh Y. A., Vakula K. A. Nickel Extraction from Poor Solutions by Sorption on Modified Coke. Solid State Phenomena. 2018. Vol. 284. pp. 785–789.
19. Belova T. P. The kinetics behind sorption of a combination of copper, nickel and cobalt ions from aqueous solutions with zeolites. Sorbtsionnye i khromatograficheskie protsessy. 2018. Vol. 18, No. 3. pp. 324–331.

Language of full-text русский
Полный текст статьи Получить
Назад