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GEOLOGY OF MINERALS
Название Carbonaceous shales of the Kamensk block: geology and ore content (South Urals)
DOI 10.17580/gzh.2020.02.02
Автор Snachev A. V., Snachev V. I., Rassomakhin M. A., Kolomoets A. V.
Информация об авторе

Institute of Geology, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, Russia:

A. V. Snachev, Head of Laboratory, Candidate of Geologo-Mineralogical Sciences, SAVant@rambler.ru
V. I. Snachev, Professor, Doctor of Geologo-Mineralogical Sciences

 

Institute of Mineralogy, South Urals Federal Research Center for Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences, Miass, Russia:

M. A. Rassomakhin, Junior Researcher

 

Orenburg State University, Orenburg, Russia:

A. V. Kolomoets, Lecturer

Реферат

The article briefly discusses the geological structure of the Kamensk block located on the eastern slope of the Southern Urals in the Alapaevsk–Chelyabinsk deep fault zone. The territory is a keyboard structure of alternating grabens and horsts composed of volcanic–sedimentary rocks of the Devonian and Carboniferous ages. A particular attention is paid to the description of the carbonaceous shales of the Birgilda Series widely developed here. It is shown that they contain up to 2.7% Corg and are of the low-carbon type. In standard petrochemical diagrams, the considered rocks fall into the fields of silicon–carbonaceous and carbonate–carbonaceous formations. These data, together with the presence of carbonates in the section, indicate their formation in the shallow and coastal-shallow areas of the sedimentary basin. Terrigenous material in the process of sedimentation underwent minimal transport, and its source was mainly of mafic and average igneous rock. In the black shale formations of the Kamensk block, industrial gold and silver contents have been established, confined to intensely dislocated, silicified and sulfidized rocks. The testing of core samples from wells showed gold contents of up to 4.6 g/t and silver up to 11 g/t. During washing of the Neo-Pleistocene weathering crust, consisting mainly of yellowish-brown loams and clays with fragments of vein quartz and carbon shales, several gold grains up to 1×1.5 mm in size were obtained. Microprobe analysis showed their heterogeneous composition. An insignificant part of the gold is represented by small, high-finely leafy flakes indicating their connection with quartz veins (gold-quartz type). Large gold is heterogeneous, has a high-quality skin of the hypergenic stage and contains noddles of copper and silver, as well as inclusions of native silver. This allows us to attribute it to the gold-sulfide type associated with carbonaceous-clay shales of the Birgilda Series. The conducted studies give the right to highly evaluate the prospects of the Kamensk block for the identification of a new gold ore object here.
The geologic work was fulfilled against the state contract, Topic No. 0246-2019-0078. The analytical studies were supported by the Regional Grant for Science, Research and Technology in 2019, Agreement No. 23 as of August 14, 2019. Microprobe tests were carried out within the framework of state-budgeted Topic No. AAAA-A19-119072390050-9.
The authors express their deep gratitude to the members of Chelyabinskgeosemka E. P. Shchulkin and B. A. Puzhakov for the offering an opportunity to participate in geological survey, as well as to the analysts from the Institute of Geology, South Urals Federal Research Center for Mineralogy and Geoecology, Russian Academy of Sciences, T. I. Chernikov, S. A. Yagudin and N. G. Khristoforov for the implemented research work.

Ключевые слова Southern Urals, Kamensk block, carbonaceous shales, black shales, Birgilda Series, noble metals, gold, silver
Библиографический список

1. Ermolaev N. P., Sozinov N. A. Stratiform mineralization in black shales. Moscow : Nauka, 1986. 172 p.
2. Yudovich Ya. E., Ketris M. P. Geochemistry of black shales. Moscow – Berlin : Direkt-Mediya, 2015. 272 p.
3. Korobeynikov A. F. Mineralogy of noble metals in nonconventional gold–platinoid ore in black shale formations. Platinum of Russia: Problems of development of the platinum metals resource base in the XXI century : collection of transactions. Moscow : Geoinformmark, 1999. Vol. 4. pp. 40–51.
4. Dodin D. A., Chernyshov N. M., Yatskevich B. A. Platinum-metal deposits of Russia. Saint-Petersburg : Nauka, 2000. 753 p.
5. Sazonov V. N., Koroteev V. A., Ogorodnikov V. N., Polenov Yu. A., Velikanov A. Ya. Gold in “black shales” of the Urals. Litosfera. 2011. No. 4. pp. 70–92.
6. Seravkin I. B., Snachev V. I. Stratiform polymetal deposits in the eastern province of the Southern Ural, Russia. Geologiya rudnykh mestorozhdenii. 2012. Vol. 54, No. 3. pp. 253–264.
7. Shumilova T. G., Shevchyuk S. S., Isaenko S. I. Metal concentrations and carbonaceous matter in the black shale type rocks of the Urals. Doklady Earth Sciences. 2016. Vol. 469. pp. 695–698.
8. Maslov A. V., Kovalev S. G., Gareev E. Z. Riphean low-carbonaceous shales of the South Urals in the context of formation of large igneous provinces. Geochemistry International. 2017. Vol. 55, No. 7. pp. 608–620.
9. Gadd M. G., Peter J. M., Jackson S. E., Zhaoping Yang, Petts D. Platinum, Pd, Mo, Au and Re deportment in hyper-enriched black shale Ni-Zn-Mo-PGE mineralization, Peel River, Yukon, Canada. Ore Geology Reviews. 2019. Vol. 107. pp. 600–614.
10. Sixiang Ling, Xiyong Wu, Yong Ren, Chunwei Sun, Xin Liao et al. Geoche mistry of trace and rare earth elements during weathering of black shale profiles in Northeast Chongqing, Southwestern China: Their mobilization, redistribution, and fractionation. Chemie Der Erde – Geochemistry. 2015. Vol. 75, Iss. 3. pp. 403–4 17.
11. Buryak V. A. Metamorphogene-hydrothermal type of gold mineralization. Geologiya rudnykh mestorozhdenii. 1975. Vol. 17, No. 2. pp. 37–46.
12. Vilor N. V. Problem of gold content of black shales. Geokhimiya. 1983. No. 4. pp. 560–568.
13. Ermolaev N. P. Phenomena of step concentration of gold in ore formation in black shales. Geologiya rudnykh mestorozhdenii. 1983. Vol. 25, No. 2. pp. 86–91.
14. Dobretsov N. L., Krivtsov A. I. Models of magmatogene–hydrothermal and metamorphogene–hydrothermal ore accumulations and criteria of discrimination. Criteria for discrimination of metamorphogene and magmatogene hydrothermal deposits : collection of scientific papers. Novosibirsk : Nauka, 1985. pp. 5–14.
15. Emsbo P. Gold in Sedex deposits. Reviews in Economic Geology. 2000. Vol. 13. pp. 427–437.
16. Emsbo P., Hofstra A. H., Lauha E. A., Griffin G. L., Hutchinson R. W. Origin of High-Grade Gold Ore, Source of Ore Fluid Components, and Genesis of the Meikle and Neighboring Carlin-Type Deposits, Northern Carlin Trend, Nevada. Economic Geology. 2003. Vol. 98, No. 6. pp. 1069–1105.
17. Groves D. I., Goldfarb R. J., Robert F., Hart C. J. R. Gold Deposits in Metamorphic Belts: Overview of Current Understanding, Outstanding Problems, Future Research, and Exploration Significance. Economic Geology. 2003. Vol. 98, No. 1. pp. 1–29.
18. Kesler S. E., Fortuna J., Zaojun Ye, Alt J. C., Core D. P. et al. Evaluation of the Role of Sulfidation in Deposition of Gold, Screamer Section of the Betze-Post Carlin-Type Deposit, Nevada. Economic Geology. 2003. Vol. 98, No. 6. pp. 1137–1157.
19. Plyusnina L.P ., Kuzmina T. V., Avchenko O. V. Modeling of Gold Sorption on Carbonaceous Material at 20-500°C and 1 kbar. Geochemistry International. 2004. Vol. 42, No. 81. pp. 755–763.
20. Cline J. S., Hofstra A. H., Muntean J. L., Tosdal R. M., Hickey K. A. Carlin-Type Gold Deposits in Nevada: Critical Geologic Characteristics and Viable Models. Economic Geology: One Hundredth Anniversary Volume (1905–2005). Littleton : Society of Economic Geologists, 2005. pp. 451–484.
21. Wood B. L., Popov N. P. The giant Sukhoi Log gold deposit (Siberia). Russian Geology and Geophysics. 2006. Vol. 47, No. 3. pp. 317–341.
22. Large R. R., Maslennikov V. V., Robert F., Danyushevsky L. V., Zhaoshan Chang. Multistage Sedimentary and Metamorphic Origin of Pyrite and Gold in the Giant Sukhoi Log Deposit, Lena Gold Province, Russia. Economic Geology. 2007. Vol. 102, No. 7. pp. 1233–1267.
23. Large R. R., Bull S. W., Maslennikov V. V. A Carbonaceous Sedimentary Source-Rock Model for Carlin-Type and Orogenic Gold Deposits. Economic Geology. 2011. Vol. 106, No 3. pp. 331–358.
24. Goldfarb R. J., Groves D. I. Orogenic gold: Common or evolving fluid and metal sources through time. Lithos. 2015. Vol. 233. pp. 2–26.
25. Lecomte A., Cathelineau M., Michels R., Peiffert C., Brouand M. Uranium mineralization in the Alum Shale Formation (Sweden): Evolution of a U-rich marine black s hale from sedimentation to metamorphism. Ore Geology Reviews. 2017. Vol. 88. pp. 71–98.
26. Parnell J., Perez M., Armstrong J., Bullock L., Feldmann J., Boyce A. J. A black sh ale protolith for goldtellurium
mineralisation in the Dalradian Supergroup (Neoproterozoic) of Britain and Ireland. Transactions of the Institutions of Mining and Metallurgy. Section B: Applied Earth Science. 2017. Vol. 126, No. 4. pp. 161–175.
27. Snachev A. V., Snachev V. I., Ardislamov F. R. Forecast Reserves of Gold in Komarovskian Carbon Sediments of Beloretsky Metamorphic Complex (The South Urals). Georesursy. 2015. Vol. 1, No. 4. pp. 99–104.
28. Snachev A. V., Snachev V. I., Romanovskaya M. A. New gold-ore occurrences in carbonaceous deposits of the Southern Urals. Moscow University Geology Bulletin. 2016. Vol. 71, No. 1. pp. 26–31.
29. Gorbachev O. V., Sozinov N. A. Some petrochemical and geochemical aspects of typification of the Pre-Cambrian carbonaceous deposits. Problems of the Pre-Cambrian sedimentary geology. Moscow : Nauka, 1985. Iss. 10. pp. 46–57.
30. Roser B. P., Korsch R. J. Provenance signatures of sandstone–mudstone suites determined using discriminant function analysis of major-element data. Chemical Geology. 1988. Vol. 67. pp. 119–139.
31. Maslov A. V., Podkovyrov V. N., Gareev E. Z., Kotova L. N. Chemical composition of sandstones and paleogeodynamic reconstructions. Litosfera. 2016. No. 6. pp. 33–55.
32. Puzhakov B. A., Shokh V. D., Shulkina N. E. et al. State geologic map of the Russian Federation. Scale 1:200 000. 2nd edition. South-Ural series. Sheet N-41-XIII (Stratum). Explanatory note. Moscow : Moskovskiy filial FGBU VSEGEI, 2018. 205 p.
33. Blyuman B. A., Dyakonov Yu. S., Krasavina T. N. Pavlov M. G. Application of termo- and X-ray characteristics of graphite for the definition of the level and type of metamorphism. Zapiski Vsesoyuznogo mineralogicheskogo obshchestva. 1974. Vol. 103, Iss. 1. pp. 95–103.
34. Snachev A. V., Shchulkin E. P. Geological Structure and Gold Mineralization of Carbonaceous Deposits of the Tyotechnaya Mountain (South Urals). Vestnik Permskogo universiteta. Geologiya. 2018. Vol. 17, No. 1. pp. 52–60.
35. Grabezhev A. I., Ronkin Yu. L., Puchkov V. N., Shardakova G. Yu., Azovskova O. B., Gerdes A. Silurian U–Pb zircon age (LA–ICP–MS) of granitoids from the Zelenodol Cu–porphyry deposit, Southern Urals. Doklady Earth Sciences. 2016. Vol. 466, Iss. 1. pp. 92–95.
36. Petrovskaya N. V. Native gold : general characteristic, typomorphism, genesis. Moscow : Nauka, 1973. 347 p.
37. Chudnenko K. V., Palyanova G. A. Thermodynamic properties of solid solutions in the Ag-Au-Cu system. Russian Geology and Geophysics. 2014. Vol. 55, No. 3. pp. 349–360.
38. Murzin V. V., Malyugin A. A. Gold typomorphism, zone of hypergenesis (in terms of the Ural). Sverdlovsk : UNTs AN SSSR, 1987. 96 p.
39. Kurskiy A. N., Bitozhents G. Ch., Mandrugin A. V., Puchkova T. V. Problem of analytical detection of platinum group metals in ore of black shale formations. Platinum of Russia: Problems of development of the platinum metals resource base in XXI century : collection of transactions. Geoinformmark, 1995. Vol. 2, Book. 1. pp. 159–174.

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