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Название Advantages and disadvantages of application of technologies of biooxidation of sulphide concentrates
Автор Krylova L. N., Vigandt K. A., Sarukhanova L. E., Adamov E. V., Zheng Zhi Hong
Информация об авторе

National University of Science and Technology “MISiS”, Moscow, Russia:

L. N. Krylova, Leading Researcher of a Chair of Concentration of Non-ferrous and Rare Metals' Ores, e-mail: krulov@yandex.ru
K. A. Vigandt, Post-Graduate Student of a Chair of Concentration of Non-ferrous and Rare Metals' Ores

E. V. Adamov, Head of Department of “MISiS” Publishing House
Zheng Zhi Hong, Post-Graduate Student of a Chair of Concentration of Non-ferrous and Rare Metals' Ores

Peoples' Friendship University of Russia, Moscow, Russia:

L. E. Sarukhanova, Assistant Professor of a Chair “Microbiology and virology”

Реферат

The advantages and disadvantages of technologies of vat biooxidation of sulfide concentrates are summarized, regarding the alternative hydrometallurgical autoclave leaching technologies, at atmospheric pressure with application of various reagents. Application of bacterial leaching has the following technical and economic advantages:
— small consumption of reagents;
— higher reactivity and rate of solids deposition in bacterial solutions (compared with solutions without bacteria);
— acceleration of bacteria oxidation of formed elemental sulfur;
— easiness of maintenance;
— low operating and capital costs, etc.
The long duration of the process is the main disadvantage of application of biooxidation technology. There are presented the results of research and technological solutions, based on the modern ideas of operation of iron-oxidizing bacteria on mineral raw materials, which implementation is conductive to significant increasing of efficiency of sulphide concentrates' biooxidation technologies, applied in industry. Increasing of the grade of oxidation of concentrate sulfides and gold recovery is possible due to the following operations:
— release of oxidized slime fraction of gold-bearing sulfide concentrate after 60–90 hours of bacterial leaching by classification in hydrocyclone;
— final leaching of the most refractory sulfides.
Carrying out the oxidation of sulfides by bacterial solutions separately from bacterial regeneration of iron (III) makes it possible to create the optimal conditions for each process and, as a result, to reduce the duration of biooxidation from 120–150 to 10–20 hours. During the use of immobilization of ironoxidizing bacteria on a neutral carrier for iron (III) regeneration, the amount of biomass increases significantly together with increasing of iron oxidation rate to 10–20 g/(l·hour). According to this, the cell resistance to adverse environmental factors is increased together with bacterial oxidation efficiency.

Ключевые слова Biooxidation, technologies, bacteria, sulfide concentrates, oxidant, advantages, disadvantages, operating costs, oxidation ratio, immobilization, oxidation level
Библиографический список

1. 2012. Available at : http://www.goldfields.co.za/com_technology.php.
2. 2012. Available at : http://www.mintek.co.za/technical-divisions/biotechnology-bio/about-bio-technology/.
3. 2012. Available at : http://www.polyusgold.com/operations/operating_mines/olimpiada/.
4. Rawlings D. E., Johnson B. D. Biomining. Berlin : Springer-Verlag, 2007. 314 p.
5. Adamov E. V., Krylova L. N., Egorov B. L., Voronin D. Yu., Panin V. V. Metallurg — Metallurgist. 2010. No. 6. pp. 62–65.
6. Gusakov M. S., Krylova L. N., Zheng Zhi Hong. Osobennosti sostava i svoystv sernokislykh bakterialnykh rastvorov zheleza (Peculiarities of composition and properties of sulfuric-acid bacterial solutions of iron). Materialy mezhdunarodnogo soveshchaniya «Sovremennye metody tekhnologicheskoy mineralogii v protsessakh kompleksnoy i glubokoy pererabotki mineralnogo syrya» (Plaksinskie chteniya – 2012) (Materials of international meeting “Modern methods of technological mineralogy in the processes of complex and deep processing of mineral resources” (Plaksin readings – 2012)). Petrozavodsk, September 12–14, 2012. pp. 311–313.
7. Polkin S. I., Adamov E. V., Panin V. V. Tekhnologiya bakterialnogo vyshchelachivaniya tsvetnykh i redkikh metallov (Technology of bacterial leaching of non-ferrous and rare metals). Moscow : Nedra, 1982. 288 p.
8. Kulebakin V. G. Bakterialnoe vyshchelachivanie sulfidnykh mineralov (Bacteria leaching of sulphide minerals). Novosibirsk : Nauka, Siberian Branch of USSR Academy of Sciences, 1978. 262 p.
9. Khmelnitskaya O. D., Mulov V. M., Panchenko A. F. Sposob pererabotki zolotosoderzhashchikh sulfidnykh kontsentratov (Method of processing of gold-bearing sulphide concentrates). Patent RF, No. 2023729. Applied : July 13, 1992. Published : November 30, 1994.
10. Gusakov M. S., Krylova L. N., Moshchanetskiy P. V., Zheng Zhi Hong. Vliyanie fiziko-khimicheskikh parametrov rastvora na okislitelnuyu aktivnost bakteriy i vyshchelachivanie sulfidnykh kontsentratov (Influence of physical and chemical parameters of solution on oxidation activity of bacterias and leaching of sulphide concentrates). IX Kongress obogatiteley stran SNG : sbornik materialov. Tom I (The IX Congress of dressers from the CIS countries : collection of materials. Volume I). Moscow, 2013. pp. 210–215.
11. Palencia I., Romero R., Mazuelos A., Carranza F. Treatment of secondary copper sulphides (chalcocite and covellite) by the BRISA process. Hydrometallurgy. 2002. No. 66. pp. 85–93.
12. Gusakov M. S., Krylova L. N., Adamov E. V. Tsvetnye Metally — Non-ferrous metals. 2011. No. 4. pp. 15–19.
13. Sinitsyn A. P., Raynina E. I. Immobilizovannye kletki mikroorganizmov (Immobilized cells of microorganisms). Moscow, 1994. pp. 100–156.
14. Biotekhnologiya metallov. Prakticheskoe rukovodstvo (Biotechnology of metals. Practical guidance). Under the editorship of G. I. Karavayko et al. Moscow : Center of interna tional projects of State Committee of Science and Technology, 1989. 375 p.
15. Cheng Y. C., Peng R. Y., Su J. C. C., Lo D. Y. Mechanism and kinetics of elemental sulfur oxidation by Thiobacillus thiooxidans in batch fermenter. Environmental Technology. 1999. No. 20. pp. 933–942.
16. Moshchanetskiy P. V., Krylova L. N. Skorost okisleniya elementnoy sery bakteriyami (Ratio of oxidation of element sulfur by bacterias). IX Kongress obogatiteley stran SNG : sbornik materialov. Tom II (The IX Congress of dressers from the CIS countries : collection of materials. Volume II). Moscow, 2013. pp. 416–420.

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