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  Tsvetnye Metally (Non-ferrous Metals)  


“Tsvetnye Metally” is the leading Russian monthly journal devoting to all problems of non-ferrous metallurgy (heavy metals, rare metals, light metals, noble metals, carbon materials, metal processing etc). Published since 1926, since 1997 has been included in "Ore and Metals" Publishing House. Volume up to 104 pages, circulation up to 1,500 copies. ISSN 0372-2929.

Its thematic plan covers all directions of scientific and technical development in non-ferrous metallurgy. The main journal sections include scientific-technical papers on heavy and light non-ferrous metals, noble metals and alloys, rare and rare earth metals, carbon materials, composites and multi-functional coatings, radioactive elements, nanostructured metals and materials, metal forming, automation etc. Theoretical and practical problems of ore mining and mineral processing, production and processing of non-ferrous metals, complex usage of ores, economics and production management, automation of metallurgical processes are widely observed in this journal.

"Tsvetnye Metally" journal publishes the papers of well-known scientists and leading metallurgists, elucidates important scientific-technical problems of development of concentrating and metallurgical enterprises, scientific-research institutes and universities in the field of non-ferrous metallurgy, presents new scientific directions and technical innovations in this area. The readers can find in this journal both the articles with applied investigations and with results of fundamental researches that make the base for new technical developments. "Tsvetnye Metally" publishes on regular base information about multiple scientific conferences and technical fairs devoted to the problems of non-ferrous metallurgy. It is internation partner and sponsor of more than 20 such international events.

"Tsvetnye Metally" is an expert peer-review edition; its editorial board incorporates leading and respectable scientists and practical specialists of non-ferrous metallurgy (44 Doctors of Engineering from total number of 53 members including 5 foreign specialists from Germany, Canada, Australia, Finland and Mongolia); it provides excellent expertise of published articles.

"Tsvetnye Metally" has English supplement "Non-ferrous Metals" published two times a year.


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The samples of electronic versions can be found here


Editorial board:
Actual address: Office 624, Leninsky prospekt 6, bld. 1
(Moscow Institute of steel and alloys, bld. A), Moscow, 119049 Russia
Mailing address: P.O. Box No. 71, Moscow, 119049, Russia
Phone / Fax: +7-495-955-01-75, 8 (926) 504-8975
E-mail: tsvetmet@rudmet.ru
Internet: www.rudmet.ru

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Based on resolution of the Supreme Attestation Committee (VAK) pf the Ministry of Education of the Russian Federation, the journal is included in the “List of periodical and scientific-technical editions published in the Russian Federation, where publication of the main results of Doctor’s theses are rec-ommended” for the theme of deposit development of solid mineral resources and for the themes of metallurgy, economics and chemistry.

2010 ã.
N1

Economics and management of production

Title

International rewiew of market of non-ferrous metals

The material is prepared by

“Norilsk Nickel” jsc, phone: (495) 787-76-34, e-mail: korneevsi@rao.nornik.ru

Title

Impact of gold industry liberalization of China, Indonesia, Brazil and Mongolia

Author

Sokolov A. M.

Author's data

Sokolov A. M., e-mail: amsokolov@mail.ru, Institute of economic researches DVO RAN

Abstract

The article presents analysis of the achieved results on the free entry way to mining and selling gold in the domestic markets of China, Indonesia, Brazil and Mongolia. It reflects the most significant government approaches to the opening of gold industry. The article contains common estimates of the countries experience during liberalization.

Key words

Liberalization, gold industry, mineral resources, state control, investment.

Bibliographical list

1. Abalkin L. I. Kurs perekhodnoy ekonomiki. - M., 1997. Vstuplenie stran dalnego zarubejya s perekhodnoy ekonomiki v VTO : opyt, polezniy dlya gosudarstv – uchastnikov SNG // Otchet TACLS, 2000. - 81 p.
2. Godin A. M. Statistika. - M. : Uzd. - torg. korp. “Dashkov I K”, 2005. - 472 p.
3. Mau V. A., Zhavoronkov S. V. Deregulirovanie rossiyskoy ekonomiki. - M.: IEPP, 2001.
5. www.anglogold.com.
6. www.eldoradogold.com.
7. www.gold.org.
8. www.barrick.com.
9. www.fcx.com.
10. www.newmont.com.

Title

Socially responsible policy of payment during the crisis time

Author

Kotlyar B. A.

Author's data

Kotlyar B. A., the general director, e-mail: tsnot@yandex.ru, The konsulting-analytical centre CNOTORGMET

Abstract

Estimation of personnel compensation policy of nonferrous metallurgy companies realized on the basis of the analysis of cash purchasing power change of workers and number of personnel during the crisis period is presented. It is offered to use an analytical method of tarification of works for strengthening of motivation and labour productivity increase.

Key words

Nonferrous metallurgy companies, financial and economic crisis, payment, cash purchasing power, personnel reduction, branch work rats.

Bibliographical list

1. Mettu R. G. // Vedomosti. 29.09.09 (N 183) P. A06.
2. Latukhina K. // Rossiyskaya gazeta. 2009. 24 sent. (N 179). P. 1.
3. Fedorinova Yu. // Vedomosti. 2009. 20 july (N 132). P. B02.
4. Vedomosti. 2009. 11 avg. P. B02.
5. Ekonomika i zhizn. 2009. 4 sent. (N 35). P. 19.
6. Bukhanova O. // Rossiyskaya bizness-gazeta. 2009. 22 sent. (N 36). P. 5.
7. Okunkova A., Kotlyar B. // Metally Evrazii. 2009. N 23. P. 50-53.
8. Petrova N. // Rossiyskaya gazeta. 2009. 25 sent. (N 181). P. 4.
9. Pismennaya E., Fedorina Yu., Terenteva A. // Vedomosti. 2009. 29 sent. (N 183). P. A03.
10. Kotlyar B. A. // Metally Evrazii. 2009. N 1. P. 52-57.
11. Kotlyar B. A. // Tsvetnye metalli. 2009. N 1. P. 7-14.
12. Kotlyar B. A. // Ibid. 1987. N 3. P. 4-11.
13. Kotlyar B. A., Elizarov E. D., Litvin A. P., Tatarnikov A. A. // Ibid. 1994. N 12. P. 4-12.
14. http://www.gmpr.ru/conference_view.php?id=24.
15. Kravchenko E. // Vedomosti. 2009. 22 sent. (N 178). P. A03.
16. Rossiyskaya gazeta. 2008. 6 noyabr. (N 230). P. 7.

Beneficiation

Title

Preliminary oxidation of bio-cake in technology of processing of sulphide gold-bearing ores and concentrates

Authors

Chubarov A. V., Belousova N. V., Drozdov S. V., Maksimenko V. V.

Authors' data

Chubarov A. V., The research and design centre «Polus», e-mail: ChubarovAV@polyusgold.ru; Belousova N. V., The Siberian Federal University, phone: (391) 254-36-27

Abstract

The new method of preparation of bio-cake to cyanidation and carbon-in-leach process of gold, a having number of advantages is offered. Preliminary processing of neutralised bio-cake by oxygen at the raised values ðÍ allows to take 92–97 % of gold, then as leaching without usage of this operation 70–80 % of metal are dissolved only.

Key words

Bio-cake, preliminary oxidation, cyanidation, carbon-in-leach process, oxygen, gold, Olimpiadinsky plant.

Bibliographical list

1. Lodeshnikov V. V. Tekhnologiya izvlecheniya zolota i serebra iz upornykh rud. - Irkutsk : Irgiredmet, 1999. - 786 p.
2. Kotlyar Yu. A., Meretukov A. S., Strizhko L. S. Metallurgiya blagorodnykh metallov. Kn. 1. - M. : MISIS, Izdatelskiy dom «Ruda i Metally», 2005. - 432 p.
3. Chubarov A. V., Belousov N. V., Kazachenko A. S., Maksimenko V. V. // Jurn. SFU. Khimiya. 2008. N 3. P. 235-241.
4. Sharlo G. Metody analiticheskoy khimii. Kolichestvennyy analiz neorganicheskikh soedineniy. - M. : Khimiya, 1965.
5. Buketov E. A. Gidrokhimicheskoe okislenie khalkogenov i khalkogenidov. - Alma-Ata : Nauka, 1975. - 326 p.
6. Mikhnev A. D. Nauchno-prikladnye osnovy pererabotki rastvorov i pulp seroshchelochnymi reagentami : avtoref. dis. … d-ra tekhn. nauk. - Krasnoyarsk, 1987.

Title

Industrial application of resin "PuroGold" for sorption of gold from cyanide-containing medium at group of companies "Petropavlovsk"

Authors

Alekseev V. N., Mutiev A. M., Volkov V. P., Nikitin N. V., Smirnov V. V.

Author's data

Volkov V. P., the chief engineer, NPO GPS, e-mail: npogps@mail.ru

Abstract

High sorption and service properties of new resin PuroGold have been revealed during six months’ industrial application at gold benefication plant "Pioneer".
The paper shows that application of new ionite in comparison with tar AM-2B will allow to reduce to 30-40 % capital input for building of regenerative and sorption shops and lower total annual operating costs on 85-90 %.

Key words

Sorption, ion-exchange resin, resin regeneration, gold, extraction, cyanidation, resaturation.

Bibliographical list

1. Pat. 2164257 RF, MPK7 P 22. B 11/08, C 22 B 3/24. Sposob izvlecheniya zolota iz rud, kontsentratov i shlamov / Tolstov E. A., Mikhin O. A., Dmitriev G. M. et al. ; zayavitel I patentoobladatel ZAO NPO “Glubokaya pererabotka” ; zayavl. 20.03.2001; opubl. 20.03.2001.
2. Smirnov V. V., Volkov V. P. et al. // Tsvetnye metally. 2005. N 1. P. 48-50.

Heavy non-ferrous metals

Title

Influence of composition of copper-lead matte on solvability of copper, lead and impurity in ferri-silicate slags

Author

Dosmukhamedov N. K.

Author's data

Dosmukhamedov N. K., the general director «Consulting Metal Service», e-mail: nurdos@bk.ru

Abstract

Thermodynamics of the system copper-lead matte-slag-gas phase with controllable parameters PO2 and PS2 is considered. Quantitative ratios of solvability of non-ferrous metals and impurity from copper-lead mattes are established. The mechanism of transition of metals from matte into slag with reference to conditions of blast and retractive blast smelting of lead raw materials is presented.

Key words

Copper-lead matte, ferri-silicate slags, solvability, metal distribution, containing, mechanical loss, mathematical processing.

Bibliographical list

1. Baskevich A. D., Sorokin M. L. // Tsvetnye metally. 1982. N 7. P. 25-28.
2.Volodchenkov S. N., Vaskevich A. D., Vanyukov A. V. // RZH Metallurgiya. 1982. N 9.
3. Vanyukov A. V., Zaytsev V. Ya. Shlaki i shteyny tsvetnoy metallurgii. - M. : Metallurgiya, 1969.
4. Dosmukhamedov N. K. // Tsvetnye metally. 2007. N 5. P 31-35.
5. Dosmukhamedov N. K. // Ibid. 2006. N 3. P. 30-33.
6. Vaskevich A. D., Mantsevich N. M., Vanyukov A. V. // Ibid. 1986. N 1. P. 15-17.
7. Vaskevich A. D., Sorokin M. L. // Ibid. 1982. N 10. P. 22-26.
8. Volodchenko S. N., Vaskevich A. D. // RZH Metallurgiya. 1982. N 8.

Title

Variant of processing of the sulphide copper concentrate by mixed method

Authors

Medvedev A. S., So Tu, Hamhash A., Gosteeva N. V., Ptitsin A. M.

Authors' data

Medvedev A. S., So Tu, Hamhash A., Gosteeva N. V., MISIS, e-mail: malochkina@yandex.ru

Abstract

Methods of processing of sulphide copper raw materials by cryoannealing with NaCl (450 °Ñ) and ÊÑl (700 °Ñ) and following leaching of cake are considered. They tried out two concentrates — erdenetsky (Mongolia) and udokansky (Russia). At that gas emission of sulphurous gases in atmosphere is completely excluded. Modes of roasting of concentrates and leaching of cakes with production of copper sulphate, kalium salts and sodium and ferrous cake as end products are developed.

Key words

Sulphide copper concentrate, roasting, leaching, copper sulphate, potash fertilizer.

Bibliographical list

1. Naboychenko S. S. Gidrometallurgiya medi. - M.: Metallurgiya, 1974.
2. Metallurgiya medi : per. S angl. pod red. L. M. Gazaryana. - M. : ONTI, 1937.
3. Khudyakov I. F., Tikhonov A. I., Deev V. I., Naboychenko S. S. Metalurgiya medi , nikelya i kobalta – M. : Metallurgiya, 1977. T. 1.

Title

The pursuit of maximal possible period for copper dendritic electrocrystallisation between its take off the cathode

Authors

Sokolovskaya E. E., Murashova I. B., Lebed’ A. B., Osipova M. L.

Author's data

Murashova I. B., GOU VPO UGTU-UPI, e-mail: el-chem@mail.ustu.ru

Abstract

During too long electrocrystallisation of dendritic copper on cathode rods the surface deposit lay restructures from branched dendritic one to rough globule scrabs. Overpotential boundary conditions are determined (ηbound) by means of chronogalvanometry method in series of constant cathodic overpotentials. This overpotential (–0,55 V) corresponds the change on control nature on deposit growth front (from mixed to pure diffusion one).The duration of continuous deposit crystallization which corresponds to ηbound, achievement forms 1,6–1,8 hour against technological 2 hours.

Key words

Copper powder, electrolysis, current density, crystallization condition, duration of deposition, overvoltage, polarization curve, hydrogen evolution.

Bibliographical list

1. Sokolovskaya E. E., Murashova I. B., Zaykov Yu. P. et al. // Tez. dokl. Mezhdunar. Shkoly-seminara “Problemy khimicheskoy tekhnologii XXI veka” - Almaty, 2007. P. 10-13.
2. Nichiporenko O. S., Pomosov A. V., Naboychenko S. S. Poroshki medi I ee splavov. - M. : Metallurgiya, 1986. - 220 p.
3. Galus Z. Teoreticheskie osnovy elektrokhimicheskikh metodov analiza. - M. : Mir, 1974. - 552 p.
4. Spravochnik khimika. - M. : Khimiya, 1964. T. 3. - 1000 p.
5. Murashova I. B., Sokolovskaya E. E., Lebed A. B. et al. // Tsvetnye metally. 2007. N 10. P. 46-51.

Ecology and protection of the environment

Title

Determination of heavy metals containing in natural water sample, snow and soils by the method of mass spectrometry with the inductively coupled plasma

Authors

Bazikova O. I., Glazunov A. L., Granovskaya N. A., Kuzin R. E.

Authors' data

Glazunov A. L., the managing laboratory GUP MosNPO «Radon», e-mail: aglazunov@radon.ru; Kuzin R. E., VNIIHT jsc, e-mail: rkuzin256@mail.ru

Abstract

The containing of heavy metals in some objects of environment of Southern Administrative District of Moscow is estimated by the method of mass spectrometry with the inductively coupled plasma (ICP-MS). Sample of snow, soils and water of surface water bodies are investigated.
The realized researches have shown necessity of complex usage of various analysis methods at studying of chemical composition of environment samples. It is necessary to notice that the priority of application of mass spectrometry ICP-MS is in area of low and ultralow concentrating of elements in samples.

Key words

Analysis, inductively coupled plasma, concentration, mass spectrometry, sample preparation, heavy metals.

Bibliographical list

1. Glazunov A. L., Granovskaya N. A., Kuzin R. E., Sklifasovskaya Yu. G. // Tsvetnaya metallurgiya. 2003. N 7. P. 38-42.
2. Glazunov A. L., Kolybanov K. Yu., Kuzin R. E., Shatalov V. V. // Tsvetnye metally. 2008. N 9. P. 86-89.
3. Gosudarstvennyy kontrol kachestva vody : spravochnik. - M. : Izd-vo standartov, 2001. - 654 p.
4. Fomin G. S., Fomin A. G. Pochva. Kontrol kachestva I ekologicheskoy bezopasnosti po mezhdunarodnym standartam : spravochnik. - M. : Protector, 2001. P. 151 – 164.
5. Berdat Dzh., Pirsol A. Prikladnoy analiz sluchaynykh dannykh : per. s angl. - M. : Mir, 1989.
6. Kelner R., Merme Zh.-M., Otto M., Vidmer G. M. Analiticheskaya khimiya. Problemy i podkhody : per. s angl. - M. : Mir, AST, 2004.

Noble metals and alloys

Title

Influence of slag compositon and fusion temperature on distribution of precious metals at reduction melting of copper gold-bearing roasted product

Authors

Strizhko L. S., Peresadi S. S.

Author's data

Strizhko L. S., phone: +7(495)237-36-33, MISIS

Abstract

Reducing smelting of preliminarily roasted copper sulfide concentrate even without addition of dope collector-phase, allows effectively extract copper and precious metals to the bottom phase (blister copper). Experimental investigation of impact of some parameters of smelting, such as concentrations of SiO2, CaO, Na2O in slag and temperature to the distribution of gold and silver was conducted, using charcoal as reductant. Obtained results show, that optimal slag composition in case of minimization of precious metals losses is: Na2O 6–7 %, CaO — 12–18 %, SiO2 — 32–36 %. Optimal process temperature is 1573 K.

Key words

Reducing smelting, gold, silver, roasted con centrate, slag.

Bibliographical list

1. Vanyukov A. V., Zaytsev V. Ya. Teoriya pirometallurgicheskikh protsessov. - M. : Metallurgiya, 1993. - 384 p.

Title

Thermodynamics of process of chemical dissolution of the silver-bearing waste of jewelry production

Authors

Sizyakov V. M., Kukolevskii A. S., Belenkiy A. M.

Author's data

Sizyakov V. M., e-mail: kafmetall@mail.ru, , St. Petersburg State Mining Institute (Technical University) named after G. V. Plehanov

Abstract

Nitrate leaching is head operation in affining of high silver content products of copper electrolysis, lead, jewellery manufactures, and also a radio-electronic breakage. The thermodynamics of silver opening processes in nitric acid solutions with participation of oxidizers and without those is analyzed in the present article. The received results have been checked up during laboratory experiments on dissolution of an silver containing waste of the jewellery industry.

Key words

Thermodynamics, affinage, silver, copper, nitric acid, oxidizing material, peroxide of hydrogen, Gibbs energy.

Bibliographical list

1. Petrov G. V., Belenkiy A. M., Boduen A. Ya., Kukolevskiy A. S. Azotnokisloe vyshchelachivanie medelektrolitnykh shlamov // Zap. Gornogo instituta. - Spb. : SPGGI, 2007. T. 170.
2. Kukolevskiy A. S., Elkin I. B. Pererabotka otkhodov yuvelirnoy promyshlennosti, soderzhashchikh zoloto, serebro i palladiy // Ibid. 2006. T. 169.
3. Sizyatov V. M., Zaytsev Yu. A., Kukolevskiy A. S. // Tsvetnye metally. 2009. N 7. P. 46-47.
4. Meretukov M. A., Orlov A. M. Metallurgiya blagorodnykh metallov. - M.: Metallurgiya, 1991, - 415 p.
5. Latimer V. Okislitelnye sostoyaniya elementov i ikh potentsialu v vodnykh rastvorakh – M. : Izd-vo inostr. lit., 1954. - 400 p.
6. Kerpelyan M. Kh., Karapetyan M. L. Osnovnye termodinamicheskie konstanty neorganicheskikh i organicheskikh veshchestv. - M.: Khimiya, 1968. - 470 p.
7. Lure Yu. Yu. Spravochnik po analiticheskoy khimii – M. : Khimiya, 1971. - 454 p.

Aluminium, alumina, carbon materials

Title

The energy-dispersive analysis of heat schemes of alumina industry

Authors

Kazakov V. G., Lipin V. A.

Author's data

Lipin V. A., e-mail: vadim.lipin@km.ru, St. Petersburg State Polytechnical University of Natural Polymers

Abstract

For power consumption decrease for alumina production the technological scheme should be optimized to satisfy thermodynamic and to technology requirements. The energy effervescive is relative characteristic of thermodynamic perfection of process. Determination of energy effervescives of heat-consuming system elements in alumina production has allowed to reveal the processes characterizing by the high inconvertibility, to plan ways on reduction or liquidation of this inconvertibility. The maximum effect is provided by schemes with high degree of regeneration of reacting heat flows.

Key words

Alumina, power consumption, heat flow, energy effervescive, energy loss, thermodynamics.

Bibliographical list

1. Eremin N. I., Naumchik A. N., Kazakov V. G. Protsessy i apparaty glinozemnogo proizvodstva / pod red. N. I. Eremina. - M. : Metallurgiya, 1980. - 360 p.
2. Leytes I. L., Sosna M. Kh., Semenov V. P. Teoriya I praktika khimicheskoy energotekhnologii. - M. : Khimiya, 1988. - 280 p.
3. Kazakov V. G., Fiterman M. Ya, Kuzmin N. P. // Tsvetnye metally.1969. N 8. P. 50-56.
4. Lipukhin E. A., Lankin V. P., Kazakov V. G. // Tsvetnye metally. 2005. N 6. P. 43-48.

Title

Investigation of gibbsite structure with various dispersion degree

Authors

Tolchev A. V., Kazantseva E. L., Larin D. D.

Authors' data

Tolchev A. V., Kazantseva E. L., e-mail: ssc_ket@mail.ru, Chelyabinsk State Pedagogical University

Abstract

Correlation of parameter c of elementary crystal cell and half-width of diffraction maximums on X-ray photogram with the average size of gibbsite crystals in a diameter is deduced from experiments. Put the case that this correlation is caused by increase in form factors of gibbsite plate crystals in process of their average size increase. Presence of microstrain in the crystal lattice γ-Al(OH)3, focused lengthways the crystallographic axis c is the reason of maximum spread at X-ray photogram of macro-crystalline gibbsite samples.

Key words

Gibbsite, aluminum hydroxide, crystal cell, X-ray photogram, diffraction maximum, crystal.

Bibliographical list

1. Godovikov A. A. Mineralogiya. - 2-e izd., pererab. i dop. - M. : Nedra, 1983. - 647 p.
2. Garshin A. P., Gropyanov V. M., Lagunov Yu. V. Abrazivnye materialy. - L.: Mashinostroenie, 1983. - 231 p.
3. Khimicheskaya entsiklopediya. V 5 t. : T. 1 / red. kol. : I. L. Knunyants et al. - M. : Sov. entsikl., 1988. - 623 p.
4. Uells A. Strukturnaya neorganicheskaya khimiya.V 3 t. : T. 2 : per. s angl. - M. : Mir, 1987. - 696 p.
5. Kalshinina A. M. // Khimiya I tekhnologiya glinozema : Trudy IV Vsesouznogo soveshchaniya. - Novosibirsk : Nauka, Sib. otd., 1971. P. 360-369.
6. Tolcheev A. V., Kleshchev D. G., Lopushan B. I. // Zhurn. prikl. khimii. 2002. T. 75, N 9. P. 1417-1421.
7. Umanskiy Ya. S., Skakov Yu. A., Ivanov A. N., Rastorguev L. N. Kristallografiya, rentgenografiya i elektronnaya mikroskopiya. - M.: Metallurgiya, 1982. - 632 p.

Magnesium, titanium, rare metals, semiconductors

Title

The research of lepidolitevitriolic opening kinetic

Authors

Samoilov V. I., Baigazova N. A.

Author's data

Samoilov V. I., «Ulbinskiy Metallurgical Plant», phone: (7232) 298-103

Abstract

Kinetics of lepidolite and sulphuric acid interreacting is investigated. The amount of apparent activation energy of lepidolite and sulphuric acid reactions is determined: Eapp = 7,6 kJ/mol. It is possible that interreacting of mechanically reactive beryl with sulphuric acid is limited by the acid molecules diffusion rate to the response surface through the layer of resultants.

Key words

Kinetics, lepidolite, sulphatisation, activation energy, leaching.

Bibliographical list

1. Plushchev V. E., Stepin B. D. Khimiya i tekhnologiya soedineniy litiya, rubidiya I tseziya. - M. : Khimiya, 1970. - 408 p.
2.Samoylov V. I. Eksperimentalnaya razrabotka perspektivnykh khimicheskikh metodov izvlecheniya berilliya I litiya iz mineralnogo syrya. - Yst-Kamenogorsk : Media-Alyans, 2006. - 551 p.
3.Voldman G. M., Zelikman A. N. Teoriya gidrometallurgicheskikh protsessov. - 4-e izdanie. - M. : Intermet Inzhiring, 2003. - 424 p.

Title

Prospects of technology improvement of carnallite unwatering

Authors

Pruttskov D. V., Krivoruchko N. P., Zabelin I. V.

Author's data

Krivoruchko N. P., e-mail: mykolakr@gmail.com, State Research Institute of the Titan, Zaporozhye, Ukraine

Abstract

Researches results on technology improvement of the second stage of carnallite unwatering with application chlorine-hydrogenous gases are presented. Variants of optimization of two-stage technology of carnallite preparation to electrolysis are offered on the basis of the result analysis results and the literary data.

Key words

Carnallite unwatering, methane, chlorine-air mix, flare, sootflakes, absorption, diffractogram, infrared spectrum.

Bibliographical list

1. Panasyuk E. B., Krayukhin A. B., Matveev V. I., Larionov A. A. // Tsvetnye metally. 2008. N 12. P. 51-54.
2. Yazev V. D., Malinovskaya E. A. Sozdanie tekhnologii I apparatury dlya obezvozhivaniya karnallita v kipyashchem sloe. - Berezniki : Grafiks, 2008. - 310 p.
3. Savinkova E. I. Obezvozhivanie karnallita : dis. … d-ra tekh. nauk. - Sverdlovsk : UPI, 1969. - 390 p.
4. Tsygankov Yu. M., Savinkov E. I., Vilnyanskiy Ya. E. // Tsvetnye metally. 1967. N 7. P. 81-84.
5. Krentsel B. A. Khlorirovanie parafinovykh uglevodorodov. - M. : Nauka, 1964. - 158 c.
6. Brenschåde W., Schumacher M. // Z. Phys. Chem. 1936. Vol. 177, N 1. S. 245–262.
7. A. s. 818206 USSR. Sposob obrabotki khlormagnievykh rasplavov / V. I. Zapadnya, V. A. Rudakov, N. V. Khaber et al.
8. Pruttskov D. V., Lysenko V. G., Zapadnya V. I. Et al. // Ukr. khim. zhurn. 1986. T. 52, N 10. P. 1026 – 1029.
9. Tubolkin A. F., Tumarkina E. S., Tarat E. Ya. Raschety khimiko-tekhnologicheskikh protsessov. - L. : Khimiya, 1982. - 246 p.
10. Fialkov A. S. Formirovanie struktury i svoystv uglegrafitovykh materialov. - M. : Metallurgiya, 1965. - 288 p.
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Nanostructured metals and materials

Title

The synthesis of the new nanostructural AgBr-TlI, AgClõBr1–õ crystals, including those alloyed with TlI

Authors

Korsakov A. S., Zhukova L. V., Zharikov E. V., Vrublevskiy D. S., Korsakov V. S.

Author's data

Korsakov A. S., e-mail: zhlv@mail.ustu.ru, UGTU-UPI

Abstract

The silver halogenide crystals transparence from visible to far-infrared region, nonhygroscopicity, nontoxicity and high plasticity are the great advantages in front of other optical materials. It is the kind of material that determines the technical characteristics of the basic optical materials and fiber-optical elements for different purposes. The radiation-resistant and transparent in 0,40–45 region new AgBr—TlI, AgClõBr1–õ crystals, including those, that are alloyed with TlI, were elaborated. The growth technologies, including unconventional multicomponent homogeneous single-phase charge and single crystals growth on the new KPC-01 device, were developed. On the base of theoretical calculations there was simulated the structure of the new defective crystals, which are the solutions of substitution. The unique crystals properties, plasticity, nonhygroscopicity, and the wide range of transparence in generally, provide the production of single- and multimode light guides of the new generation for middle and far-infrared regions.

Key words

Solid AgBr—TlI solutions, thermal-zone crystallization–synthesis method, crystals.

Bibliographical list

1. Zhukova L. V., Primerov N. V., Korsakov A. S. et al // Neorg. materialy. 2008. T. 44, N 12. P. 1516-1521.
2. Nauch. trudy Giredmeta. T. 29. - M. : Metallurgiya, 1970. - 160 p.
3. Zayavka 2009106499 RF / Korsakov A. S., Grebneva A. A., Zhukova L. V., Chazov A. I. ; zayavl. 24.02.2009.
4. Zayavka 2009106541 RF / Chazov A. I., Zhukova L. V., Korsakov A. S., Zhukov V. V. ; zayavl. 24.02.2009.
5. Pat. 2288489 RF, MPK G 02 B 1/02. Opticheskiy monokristall / Zhukova L. V., Zhukov V. V., Pilugin V. P. ; zayavl. 13.05.2005 ; opubl. 27.11.2006, Bul. N 33.
6. Pat. 2287620 RF, MPK C 30 B 29/12. Sposob polucheniya kristallov s defectami na osnove tverdykh rastvorov galogenidov metallov / Zhukova L. V., Zhukov V. V., Pilugin V. P. ; zayavl. 13.05.2005 ; opubl. 20.11.2005; opubl. 20.11.2006, Bul. N 32.
7. Pat. 2160795 RF, MPK7 C 30 B 7/04. Sposob polucheniya vysokochistykh veshchestv / Zhukova L. V., Zhukov V. V., Kitaev G. A.; zayavl. 07.07.1999; opubl. 20.12.2000, Bul. N 33.
8. Zelyanskiy A. V., Zhukova L. V., Kitaev G. A. // Neorg. materialy. 2001. T. 37, N 5. P. 622-625.
9. Zhukova L. V., Kitaev G. A., Kozlov F. N. // Zhurn. fiz. khimii. 1978. T. 52, N 7. P 1692-1695.
10. Kitaev G. A., Zhukova L. V., Kozlov F. N. // Ibid. 1980. T. 54, N 8. P. 2032-2036.
11. Zharikov E. V., Prihod`ko L. V., Storozhev N. R. // J. Crystal Growth. 1990. Vol. 99. P. 910–914.
12. Ormont B. F. Vvedenie v fizicheskyyu khimiyu i kristallokhimiyu poluprovodnikov. - M. : Vysshaya shkola, 1973. - 658 p.
13. Groznetskiy V. V., Zhuravlev V. D., Kitaev G. A., Zhukova L. V. // Zhurn. neorg. khimii. 1985. T. 30, N 4, P. 1033-1035.

Title

Increase of plasticity and viscosity of alloy E635 for load-bearing elements of fuel assemblies of reactors

Authors

Markelov V. A., Shishov V. N., Sablin M. N., Aktuganova E. N., Kropachev S. Yu.

Author's data

Markelov V. A., e-mail: markelov@bochvar.ru, BNIINM jsc

Abstract

Possibilities of increase of technological and operational characteristics of zirconia alloy E635 by control of degree of recrystallizing, the size, density and uniformity of distribution of particles of the second phase are considered. In practice such possibilities for alloy E635 are realised by optimization of the scheme of processing of pipes for guide channels and the central pipe of fuel assembliess of reactors and improvement, at the expense of updating of technology, structurally-phase condition of strips for corners of rigidities of skeleton.

Key words

Alloy E635, plasticity, viscosity, structurally-phase condition, degree of recrystallizing, particles of the second phase, guide channels, central pipe, rigidity corners, fuel assemblies.

Bibliographical list

1. Markelov V., Novikov V., Nikulina A. et al. // Proc. of the 6-th Intern. Conf. WWER Fuel Performance, Modelling and Experimental Support. — Albena (Bulgaria). 19–23 Sept. 2005. P. 188–193.
2. Samoylov O. B. // Yadernoe toplivo dlya AES. - M. : OAO MSZ, 2003. P. 2-6.
3. Nikulina A. V., Markelov V. A., Peregud M. M. et al. // Zirconium in the Nuclear Industry : Eleventh International Symp. ASTM STP 1295. 1996. P. 785–804.
4. Nikulina A. V., Markelov V. A., Peregud M. M. et al. // J. Nuclear Materials. 1996. Vol. 238. P. 205–210.
5. Nikulina A. V., Shishov V. N., Peregud M. M. et al. // Effects of radiation on materials : Eighteenth Intern. Symp. ASTM STP 1325. 1999. P. 1045–1061.
6. Shishov V. N., Markelov V. A., Nikulina A. V. et al. // Vopr. atomnoy nauki I tekhniki, seriya : Materialovedenie i novye materialy. 2006. Vyp. 1 (66). P. 313-328.
7. Fateev B. M., Nikulin S. A., Markelov V. A. et al. // Ibid. 1993. Vyp. 1(48). P. 25-30.
8. Nikulin S. A., Goncharov V. I., Markelov V. A., Shishov V. N. // Zirconium in the Nuclear Industry : Eleventh Intern. Symp. ASTM STP 1295. 1996. P. 695–709.
9. Nikulin S. A. // Fizika metallov I metallovedenie. 1996. T. 81, vyp. 3. P. 142-159.
10. Markelov V. A., Aktuganova E. N., Zheltkovskaya T. N. et al. // Sb. tez. dokl. 2nd Evraziyskoy nauch.-prakt. konf. “Prochnost neodnorodnykh struktur”. - M. 20-22 aprelya, 2004. P. 29.
11. Nikulin S. A., Shtremel M. A., Markelov V. A. // 1-st. European Mechanics of Materials Conf. on Local Approach to Fracture. — Fontainebleau, 9–11 Sept., 1996. P. 133–143.
12. Markelov V. A., Nikulin S. A., Gusev A. U. et al. // Vopr. atomn. nauki i tekhniki, seriya : Materialovedenie I novye materialy. 1993. Vyp. 1(48). P. 37-43.
13. Markelov V. A., Nikulin S. A., Gusev A. Yu. et al. // Ibid. P. 21-25.
14. Markelov V. A., Rafikov V. Z., Nikulin S. A. et al. // Fizika metallov i metallovedenie. 1994. T. 77, vyp. 4. P. 70-79.
15. Markelov V. A., Shishov V. N., Zheltovskaya T. N., Khokhunova T. N. // Sb. dokl. 4th mezhotraslevoy konf. po reaktornomu materialovedeniyu. - Dimitrovgrad, 15-19 maya 1995. T. 2. P. 27-38.
16. Nikulin S. A., Markelov V. A., Goncharov V. I. Et al. // Izv. RAN. Metally. 1995. N 1. P. 62-68.
17. Markelov V. A., Novikov V. V., Nikylina A. V. et al. // Vopr. atomnoy nauki I tekhniki, seriya : Materialovedenie i novye materialy. 2006. Vyp. 2 (67). P. 63-72.
18. Pat. 2261765 RF, MPK B 21 B 3/00 / Sposob polucheniya ploskogo profilya iz tsirkoniy-niobievykh splavov. 2005.

Metal processing

Title

Production of metal powders by mechanical crushing of chip and scrap, production of blowy pieces by the electropulse method

Authors

Krasnov A. A., Kostrov K. V., Silin A. Yu., Samuilov S. D.

Author's data

Samuilov S. D., e-mail Sam.Mhd@mail.ioffe.ru, FTI named after A. F. Ioffe RAN

Abstract

Results of experiments on metal chip crushing and other light scrap at industrial rotary jet mills developed in LLC «New technologies – engineering» (St. Petersburg) are resulted. Problems of high efficiency mills creation and maintenance of crushing in the inert media are solved. The wide spectrum of metals is investigated. Possible spheres of powders application are analyzed. The paper shows, that it is possible to produce from a powder the materials with porosity of ~50 % with use of electropulse technology.

Key words

Scrap metal, metal chip, metal powders, mechanical grinding, rotary jet mills, porous metals, electropulse technology of metal chip briquetting.

Bibliographical list

1. Utilizatsiya tverdykh otkhodov : v 2 t. : sokr. Per. s angl. / pod red. D. Vilsona. - M. : Stroyizdat, 1985.
2. Tamurov V. P. et al. Oborudovanie po pererabotke vtorichnykh chernykh metallov. - M. : Metallurgiya, 1976. - 288 p.
3. Evdokimov A. Ya. // Rynok vtorichnykh metallov. 2001. N 5. P. 38-40.
4. Shmitts K. // Tsvetnyu metally. 2006. N 9. P. 109-113.
5. Abramova K. B., Samuylov S. D., Filin Yu. A. // Tsvetnye metally. 1998. N 12. P. 70-74.
6. Abramova K. B., Samuylov S. D. // Rynok vtorichnykh metallov. 2005. N 2/28. P. 50, 51.
7. Abramova K. B., Bocharov Yu. N., Samuylov S. D., Shcherbakov I. P. // Zhurnal tekhnicheskoy fiziki. 2001. T. 71, vyp. 4. P. 122-127.
8. Bocharov Yu. N., Krestyaninov D. A., Samuylov S. D., Filin Yu. A. // Nauchno-tekhnicheskie vedomosti SpbGPU. 2008. N 4. P. 125-130.
9. Samuylov S. D. // Chernye metally. 2009. N 2. P. 14-19.
10. Rudskoy A. I., Girshov V. L. // Metalloobrabotka. 2005. N 6 (30).
11. Ivanov D. O., Aksenov A. A., Rupasov S. P. // Tsvetnye metally. 2007. N 12. P. 74-81.
12. Ryabicheva S. A., Tsirkin A. T., Beloshitskiy N. V. // Poroshkovaya metallurgiya. 2007. N 5/6. P. 111-117.
13. Ryabicheva L. A., Nikitin Yu. N., Tsyrkin A. T., Markov V. L. // Metalloobrabotka. 2004.N 3 (21).
14. Grigorev A. K., Grokholskiy B. P. Poroshkovaya metallurgiya i primenenie kompozitsionnykh materialov. - L. : Lenizdat, 1982. - 143 p.
15. Fetisov G. P., Karpman M. G. et al. Materialovedenie i tekhnologiya metallov. - M. : Vyssh. Shk., 2000. - 638 p.
16. Kuimov S. D. // Tsvetnye metally. 2007. N 4. P. 96-100.
17. Narva V. K., Shugaev V. A., Vin T., Monina L. V. // Tsvetnye metally. 2007. N 4. P. 101-104.
18. Shubert G. Podgotovka metallicheskikh vtorichnykh materialov (resursy, klassifikatsiya, izmelchenie) : per. s nem. - M. : Metallurgiya, 1989. - 360 p.

Title

Development of superduty bar production from constructive and electrotechnical bronzes at Kamensk-Uralsky non-ferrous metal working plant

Authors

Bokov N. F., Kazantsev E. A., Zheleznyak L. M., Kuzmina Å. V., Mazunina Ò. V.

Authors' data

Bokov N. F., Kazantsev E. A., Zheleznyak L. M., e-mail: bsp@mtf.ustu.ru, UGTU-UPI

Abstract

Highly productive technological schemes of superduty bar production with diameters 6–130 mm from constructional and electrotechnical bronzes, including new, nonconventional for factory marks alloy are realized. Experiments are realized on the basis of results of the research works spent in a foundry-melting production cycle at hot (pressing) and cold (drawing) of plastic flow and also at thermodeformation processing. Productive fully satisfies the rigid stringent technical requirements of Russian and foreign standards on stability of mechanical and electrotechnical characteristics, macrogeometry and surface condition.

Key words

Bronze, plastic deformation, bars, highly productive technologies, industrial parties.

Bibliographical list

1. Bokov N. F., Sulitsin A. V., Mokeev V. E., Zheleznyak L. M., Lonchakova O. Yu. // Tsvetnye metally. 2006. N 7. P. 83-86.
2. Dashkevich O. N., Bokov N. F., Zheleznyak L. M., Kuzmina E. V., Khayrulina G. P. // Tsvetnye metally. 2008. N 3. P. 104-107.
3. Nikolaev A. K., Novikov A. I., Rozenberg V. M. Khromovye bronzy. - M. : Metallurgiya, 1983. - 177 p.
4. Nikolaev A. K., Rozenberg V. M. Splavy dlya elektrodov kontaktnoy svarki. - M. : Metallurgiya, 1978. - 96 p.
5. Rozenberg V. M., Nikolaev A. K. // Tsvetnye metally. 1972. N 8. P. 65-70.
6. Pat. 2239670 RF. Sposob termodeformatsionnoy obrabotki izdeliy iz khromovoy bronzy / Snigirev A. I., Zheleznyak L. M., Miller A. V.; opubl. 10. 11. 2004.
7. TU 48-21-249-2006. Prutki kruglye iz bronzy marki BrAZhNMts9-4-4-1. Tekhnicheskie usloviya. - Vved.2006 -12-01.
8. DIN EN 12163–1998. Med i madnye splavy. Prutki obshchego naznacheniya ; opubl. 01. 04. 1998.
9. GOST 1628-78. Prutki bronzovye. Tekhnicheskie usloviya. - Vved. 1980-01-01. - M. : Izd-vo standartov, 1978. - 16 p.
10. TU 48-21-354-74. Profili bronzovye. - Vved. 1974-06-01.
11. GOST 18175-78. Bronzy bezolovyannye, obrabatyvaemye davleniem. Marki. - Vved. 1979-01-01. - M. : Izd-vo standartov, 1978. - 8 p.
12. Shevakin Yu. F., Grabarnik L. M., Nagaytsev A. A. Pressovanie tyazhelykh tsvetnykh metallov i splavov. - M. : Metallurgiya, 1987. - 246 p.
13. Pat. 2152287 RF. Kristallizator dlya nepreryvnogo litya slitkov / Kleynburg I. P., Zheleznyak L. M., Kositsina I. I. ; opubl. 10.07.2000.

Title

The self-regulatory mechanism of process of asymmetrical cogging for increase of accuracy of the geometrical sizes and bar flatness improvement

Author

Maksimov E. A.

Author's data

Maksimov E. A., e-mail: maksimov50@mail.ru, «Intray»

Abstract

The new self-regulatory mechanism of process of asymmetrical cogging is offered. Thus capillary tension on borders of deformation zone and land length with opposite friction forces are regulators of gage and bar drawing, characterizing the geometrical sizes accuracy.
Experimental data of the self-regulatory mechanism of process of asymmetrical cogging on longitudinal, cross gage interference and bar flatness is listed.

Key words

Asymmetrical cogging, bar drawing, geometrical sizes, deformation, gage interference.

Bibliographical list

1. Sinitsyn V. G. Nesimetrichnaya prokatka listov I lent. - M. : Metallurgiya, 1984. - 167 p.
2. Sinitsyn V. G.,Schastlivtsev N. S., Eyshteyn S. S. et al. // Tsvetnye metally. 1972. N 6. P. 56-58.

 
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